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KTP

KTP Nonlinear Crystal Potassium Titanyl Phosphate

 

KTP Nonlinear crystal Potassium Titanyl Phosphate is the most commonly used material for frequency doubling of Nd-doped lasers, particularly at the low or medium power density. It is widely used for frequency mixing to generate Red/Green/Blue output, and for OPO and OPA to generate visible to mid-infrared tunable output. It is also used for many E-O devices such as Q-switches and E-O modulators.

  

Technical parameters of KTP

Tolerance of cutting angle

△θ≤±0.25°,△φ≤±0.25°

Tolerance of dimension

Dimension+0/-0.1 mmL±0.1mm

Flatness

λ/10 @ 632.8nm

Wavefront distortion

λ/8@ 632.8nm

Surface quality

10/5 per MIL-O-13830A

Parallelism

20

Perpendicularity

5

Clear Aperture:

> 90%

Chamfer:

< 0.1 mm @ 45°

Size

Upon customer request

Coating

AR/HR coating upon customer’s request

Damage Threshold

750MW/CM2 at 1064nm, TEM00, 10ns, 10Hz

Quality Warranty Period

One year under proper use

 

Optical and Nonlinear properties of KTP

Transparency Range

350~4500nm

SHG Phase Matchable Range

497 ~ 1800nm (Type II)

Therm-optic Coefficient (/, λ in μm)

dnx/dT=1.1X10-5

dny/dT=1.3X10-5

dnz/dT=1.6X10-5

Absorption Coefficients

<0.1%/cm at 1064nm <1%/cm at 532nm

Angle Acceptance

14.2mrad·cm (φ);55.3mrad·cm (θ) for Type II SHG of a Nd:YAG laser at 1064nm

Temperature Acceptance

24°C·cm for Type II SHG of a Nd:YAG laser   at 1064nm

Spectral Acceptance

0.56nm·cm for Type II SHG of a Nd:YAG laser at 1064nm

Walk-off Angle

0.55° for Type II SHG of a Nd:YAG laser at 1064nm

NLO Coefficients

deff(II)≈(d24 - d15)sin2Φsin2θ - (d15sin2Φ +   d24cos2Φ)sinθ

Non-vanished NLO susceptibilities

d31=6.5 pm/V d24=7.6 pm/V

d32= 5 pm/V d15=6.1 pm/V

d33=13.7 pm/V

Sellmeier Equations (λ in μm)

nx2=3.0065+0.03901/(λ2-0.04251)-0.01327λ2

ny2=3.0333+0.04154/(λ2-0.04547)-0.01408λ2

nz2=3.3134+0.05694/(λ2-0.05658)-0.01682λ2

Electro-optic Coefficients:

Low and High frequency (pm/V)

r13

9.5 and 8.8

r23

15.7and 13.8

r33

36.3 and 35

r51

7.3 and 6.9

r42

9.3 and 8.8

Relative Dielectric Constant

εeff=13

 

Physical properties of KTP crystal

Crystal Structure

Orthorhombic, space group Pna21,point group mm2

Lattice Parameter

a=6.404Å, b=10.616Å, c=12.814A, Z=8

Melting Point

About 1172°C

Mohs Hardness

5

Density

3.01 g/cm3

Refractive indices

nX = 1,7404; nY = 1,7479; nZ = 1,8296 @1064 nm

Thermal Conductivity

13W/m/K

Thermal Expansion Coefficients

ax=11x10-6/, ay=9x10-6/, az=0.6x10-6/